磁性花生壳负载钯催化剂的制备及催化氨硼烷释氢性能

以高锰酸钾改性后的花生壳为原料,通过共沉淀法制备了磁性花生壳(PSK-Fe_3O_4)复合材料,并以其为载体制备了磁性花生壳负载钯催化剂(Pd/PSK-Fe_3O_4).以XRD、FT-IR、TEM、XPS、TG等表征手段对该催化剂进行了表征,并将其应用于催化氨硼烷水解释氢.结果表明:Pd/PSK-Fe_3O_4催化剂在催化氨硼烷水解反应中表现出较好的催化活性,其转换频率(TOF)为6.7 mol_(H2)·mol_(Pd)~(-1)·min~(-1),表观活化能(E_(app))为28.0 kJ mol~(-1).Pd/PSK-Fe_3O_4催化氨硼烷水解释氢反应对于催化剂浓度和氨硼烷浓度的反应级数分别为一级和零级.此外,循环实验表明该催化剂具有较好的循环稳定性.     

柞蚕蛹皮制甲壳质

通过对柞茧蛹皮的成分、结构进行物理化学及电镜分析 ,从而确定其含有的主要成分及含甲壳质的数量 ,进而认定蛹皮的可利用价值。对提取甲壳质的工艺进行了初步研究 ,并对柞蚕蛹皮制甲壳质和虾蟹制甲壳质的性能作了比较分析     

核壳胶粒增韧改性聚丙烯研究2. 分散相性质的影响

以甲基丙烯酸缩水甘油酯接枝改性聚丙烯 ( PP- g- GMA)作为界面改性剂 ,采用尺寸可控的聚丙烯酸丁酯 ( PBA) /聚甲基丙烯酸甲酯 ( PMMA)反应性核壳胶粒与聚丙烯 ( PP)进行反应共混 ,研究了核壳胶粒及胶粒核层交联度对 PP/PP- g- GMA/核壳胶粒共混物冲击力学性质的影响 .结果表明 ,当核壳胶粒在 0 .38～ 1 .58μm变化 ,较大尺寸的胶粒有利于增韧 ;随胶粒核层的交联剂浓度由 0增加到 5%,发现存在最适合于增韧的胶粒核层交联度 .研究还显示 ,核壳胶粒尺寸与核层交联度对 PP增韧的影响之间存在相互作用 ,最适合于增韧的胶粒核层交联度 (交联剂浓度 )随胶粒尺寸变化而改变 ,这可用空穴化 /剪切屈服机理来加以解释     

有限变形圆柱壳结构的运动学方程

以有限变形连续体的最小加速度原理为基础，导出了在任意位置受到横向集中动力载荷作用下的闭合圆柱壳的有限变形运动方程，该方程反映了膜力效应和转动惯性效应；推导过程直接、简便、不易出错，同时指出，所得到的控制方程对于描述有限变形的冲击动力学问题是适宜的。     

带Fuzzy外壳和Boole心脏的险象识别逻辑

结合新近发展起来的Ｆｕｚｚｙ命题逻辑的思想和组合线路险象识别技术的背景，改造Ｇｏｅｄｅｌ蕴算子和公式代数的赋值格，构造了另一种带Ｆｕｚｚｙ外壳和Ｂｏｏｌｅ心脏的险象识别逻辑，对其进行了语义地研究，得到了若干有趣的结果。     

高剥离态离子nl壳层的能量计算

采用改进的屏蔽氢离子模型计算高剥离态离子的ｎｌ壳层能量，并与实验值及其他理论值进行了比较。     

高炉风口小套设计的理论思考与建议

利用计算机风口烧损过程数模，对市场现有几种典型风口小套进行了简单剖析，提出了烧损风口小套的“铁水流股寿命”和“铁水流股破坏能力”的概念，分析了二者对风口烧损过程的作用机理及二者在实际高炉冶炼过程中的存在规律，在此基础上设计的折流式风口小套在数十个厂家的应用中取得了理想效果，为炼铁厂在不投资改造给水设备的条件下，设计低成本长寿风口提供了参考意见。     

What is the matter with Corbicula fluminea (Mollusca: Bivalvia: Cyrenidiae)? Occurrence of unusual shell erosion in Northern Italy

ABSTRACT

Corbicula fluminea is a bivalve considered to be among the 100 worst invasive species in Europe due to its economic and ecological impacts in freshwater ecosystems. Here, we report for the first time a phenomenon of shell erosion observed in two distinct populations of C. fluminea collected in 2015 from two semi-natural small streams of the River Ticino hydrographic basin (Northern Italy). We measured several biometric variables in order to quantify the shell damage: length and thickness of the right valve and the shell free dry weight of each specimen and compared results with those of ‘normal’ populations from another stream of the same area. Our results confirmed that there was abnormal shell erosion and a reduction in shell thickness in both populations. We hypothesised several potential causes for the observed erosion, but none of them could provide sufficient explanation: neither the pH of the water, nor the level of calcium or total hardness of the water or granulometry of the substrates differed among streams. Similarly, predation pressure cannot be considered a reasonable explanation, since in the study area only a few animals actively prey on these bivalves and the marks they leave on the shells are completely different from the ones observed on our specimens. Lastly, we hypothesised that the bivalves may have been affected by a disease or parasitic infestation that had weakened their shells or prevented them from self-repairing and identified a fungal parasite that could possibly cause a disease to C. fluminea, namely the Ascomycota Geotrichum candidum. However, this species occurred only in one of the two abnormally eroded populations. In conclusion, a valid explanation for the morphological alteration that our study revealed has yet to be found.     

超重核区的双幻性质研究

应用V-S公式、连续介质模型和Strutinsky壳修正能量理论计算结果，对SHEs区的核素进行α衰变能及寿命、基态形状及其变化和壳能级结构进行了研究。并对各种理论模型计算结果进行比较分析，认为298114最有可能成为超重核中唯一的球形双幻核。     

贵阳乌当古生代腕足动物化石壳质成份的初步研究

通过对乌当古生代五组腕足动物化石壳和围岩的光谱半定量及红外光谱测试扫描,发现化石壳的化学成份、矿物成份和围岩关系密切,说明石化过程中,置换、交代作用进行得比较完全,这种研究有明显意义。